Optimization of Perovskite Solar Cell Performance Using Graphene in the Electron Transport Layer and Using Anti-Reflection Coating

Document Type : Original Article

Authors

Department of Electrical and Electronics Engineering, University of Sistan and Baluchestan, Zahedan, Iran

Abstract
One of the most important challenges facing perovskite solar cells is to increase their efficiency. Different methods can be used to increase the efficiency of this solar cells, where changing the layers around the perovskite is one approach. In this paper, the structure of perovskite solar cells has been investigated, simulated, and optimized. In these simulations, three different materials including TiO2, graphene, and a combination of these two materials with different percentages of graphene in the electron transport layer (ETL) is used. The results show that the combination of 5% graphene with TiO2 provides the best performance with a maximum current density of 22 mA/cm². Furthermore, the effect of the thickness of different layers on the efficiency of the solar cell has been investigated, and the impact of changes in the perovskite layer, hole transport layer, electron transport layer, and transparent oxide layer on the efficiency has been studied. Additionally, a particle swarm optimization method has been used to achieve the best possible structure. Finally, with the application of an anti-reflective coating (ARC) made of silicon dioxide (SiO2), the efficiency of the structure increased to 16.49%.

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- مراجع
[1]   S. S. Gharahyali, Zero to One Hundred of Solar Energy, Dibagaran Cultural and Artistic Institute, Tehran, 2019. (in persian)
[2]  S. Maranghi, M. L. Parisi, R. A. Sinicropi, Environmental Profile of the Manufacturing Process of Perovskite Photovoltaics: Harmonization of Life Cycle Assessment Studies, Energies, Vol. 12, No. 19, pp. 1-19, 2019.
[3] R. A. Afre, D. Pugliese, Perovskite Solar Cells: A Review of the Latest Advances in Materials, Fabrication Techniques, and Stability Enhancement Strategies, Micromachines, Vol. 15, No. 2, pp. 192, 2024.
[4]  N. M. Park, Perovskite Solar Cells: An Emerging Photovoltaic Technology, Materials Today, Vol. 18, No. 2, pp. 65–72, 2015.
[5]  C. Yang, W. Hu, J. Liu, C. Han, Q. Gao, A. Mei, Y. Zhou, F. Guo, H. Han, Achievements, Challenges, and Future Prospects for Industrialization of Perovskite Solar Cells, Light: Science & Applications, Vol. 13, No. 1, pp. 227, 2024.
[6]  L. Gu, F. Zhiyong, Perovskite/Organic-Semiconductor Heterojunctions for Ultrasensitive Photodetection, Light: Science & Applications, Vol. 6, pp. e17090, 2017.
[7] G. M. Meheretu, A. K. Worku, M. T. Yihunie, R. K. Koech, G. A. Wubetu, The Recent Advancement of Outdoor Performance of Perovskite Photovoltaic Cells Technology, Heliyon, Vol. 10, No. 17, pp. e36710. 2024.
[8] M. Dadashbeik, D. Fathi, M. Eskandari, Design and simulation of perovskite solar cells based on graphene and TiO₂/graphene nanocomposite as electron transport layer, Solar Energy, Vol. 207, pp. 917–924, 2020.
[9] N. Islam, M. Yang, K. Zhu, Z. Fan, Mesoporous scaffolds based on TiO₂ nanorods and nanoparticles for efficient hybrid perovskite solar cells, Journal of Materials Chemistry A, Vol. 48, pp. 24315-24321, 2015.
[10] B. Feleki, G. Bex, R. Andriessen, Y. Galagan, F. Di Giacomo, Rapid and low temperature processing of mesoporous TiO₂ for perovskite solar cells on flexible and rigid substrates, Materials Today Communications, Vol. 13, pp. 232–240, 2017.
[11] C. Motta, F. El-Mellouhi, S. Kais, N. Tabet, F. Alharbi, S. SanvitoMotta, Revealing the role of organic cations in hybrid halide perovskite CH₃NH₃PbI₃, Nature Communications, Vol. 6, pp. 7026, 2015.
[12] F. El-Mellouhi, E. T. Bentria, S. N. Rashkeev, S. Kais, F. H. Alharbi, Enhancing Intrinsic Stability of Hybrid Perovskite Solar Cell by Strong, yet Balanced, Electronic Coupling, Scientific Reports, Vol. 6, pp. 30305, 2016.
[13] A. Giuri, R. Mastria, A. RizzGiuri, The Path Toward Metal-Halide Perovskite Industrialization, Cell Reports Physical Science, Vol. 10, pp. 102245, 2024.
[14] C. Rossel, Perovskites: A Class of Materials with Multiple Functionalities and Applications, Europhysics News, Vol. 49, No. 3, pp. 10–13, 2018.
[15] M. Ali, Z. Bibi, M.W. Younis, M. Mubashir, M. Iqbal, M. U. Ali, M. Asif Iqbal, An Accurate Prediction of Electronic Structure, Mechanical Stability, and Optical Response of BaCuF₃ Fluoroperovskite for Solar Cell Application, Solar Energy, Vol. 267, pp. 112199, 2024.
 [16] J. Han, K. Park, S. Tan, Y. Vaynzof, J. Xue, E. W.-. Diau, M. G. Bawendi, J.-W. Lee, I. Jeon, Perovskite solar cells, Nature Reviews Methods Primers, Vol. 5, pp. 3, 2025.
[17] S. N. R. Nanduri, M. K. Siddiki, G. M. Chaudhry; Y. Z. Alharthi, Numerical Simulation and Performance Optimization of Perovskite Solar Cell, in 2017 IEEE 44th Photovoltaic Specialist Conference (PVSC), Washington, DC, USA, pp. 1018-1021, 2017.
[18] Z. Ku, Y. Rong, M. Xu, T. Liu, H. Han, Full printable processed mesoscopic CH₃NH₃PbI₃/TiO₂ heterojunction solar cells with carbon counter electrode, Scientific Reports, Vol. 3, pp. 3132, 2013.
[19] F. Biccari, F. Gabelloni, E. Burzi, M. Gurioli, S. Pescetelli, A. Agresti, A. E. D. R. Castillo, A. Ansaldo, E. Kymakis, F. Bonaccorso, A. D. Carlo, A. Vinattieri, Graphene-Based Electron Transport Layers in Perovskite Solar Cells: A Step-Up for an Efficient Carrier Collection, Advanced Energy Materials, Vol. 7, No. 21, pp. 1701349, 2017.
[20] H. Zhou, Q. Chen, G. Li, S. Luo, T.-B. Song, , H.-S. Duan, Z. Hong, J. You, Y. Liu, Y. Yang, Interface Engineering of Highly Efficient Perovskite Solar Cells, Science, Vol. 345, No. 6196, pp. 542–546, 2014.
[21] E. Barruna, A Saniah, R. Bhaskara, S. F. Rahman; A. Zulfia, N. R. Poespawati "Carbon Nanotubes, Graphite, and Reduced Graphene Oxide in CuSCN Incorporated Carbon Electrodes in Perovskite Solar Cells, in Proceedings of the 11th Electrical Power, Electronics, Communications, Control, and Informatics Seminar (EECCIS 2022), IEEE, Malang, Indonesia, pp. 119–122, 2022.
[22] S. Santosh, S. Patel, M. M. Malik, P. K. Patel, Recent Advancements in Applications of Graphene to Attain Next-Level Solar Cells, C, Vol. 9, No. 3, pp. 70, 2023.
[23] C. Zhang, Applications of Graphene in Perovskite Solar Cells, Highlights in Science, Engineering and Technology, Vol. 111, pp. 241–245, 2024.
[24] Stauffer, Nancy W. Transparent, Flexible Solar Cells, MIT News, 28 July 2017.
 [25] E. Karimi, S. M. Bagher Ghoreishy, Designing and optimization of perovskite solar cells using different electron-transporting materials, Journal of Research on Many body Systems, Vol. 9, No. 17, pp. 123-133 , 2010. (in persian)
[26] J. Han, K. Park, S. Tan, Y. Vaynzof, J. Xue, E. Wei-Guang Diau, M. G. Bawendi, J.-W. Lee, I. Jeon, Perovskite solar cells, Nature Reviews Methods Primers, Vol. 5, No.3, pp. 1-27, 2025.
[27] M. Afroz, R. K. Ratnesh, S. Srivastava, J. Singh, Perovskite solar cells: Progress, challenges, and future avenues to
clean energy, Solar Energy, Vol. 287, pp. 113205, 2025.
[28] M. Gantumur, Md. Shahiduzzaman, M. I. Hossain, Md. Akhtaruzzaman, M. Nakano, M. Karakawa, J. Michel Nunzi,
T. Taima, Revolutionizing light capture: a comprehensive review of back-contact perovskite solar cell architectures, Materials Today, Vol. 90, pp. 441-465, 2025.
[29] S. Sucharitakul, V. Yarangsi, S. Thanasanvorakun, T. Sintiam,
S. Yarin, K. Hongsith, S. Phadungdhitidhada, S. Choopun, Enhanced perovskite solar cells with TiO2-Graphene nanocomposite quantum dots in electron transport layer, Electrochimica Acta, Vol. 521, pp. 145901, 2025.
[30] T. Sewela, R. O. Ocaya, T. D. Malevu, Recent insights into the transformative role of Graphene‐ based/TiO2 electron transport layers for perovskite solar cells, Energy Science & Engineerin, Vol. 13, pp. 4-26, 2024.
 [31] A. Daraiee, Simulation and Optimization of the Performance of a Graphene/Perovskite-Based Solar Cell, Master’s Thesis, Central Library of Shahrood University of Technology, Department of Electrical Engineering, 2019. (in persian)
 [32] M. Norouzi, H. Fatemi Imam Gheis, Z. Monfared, A. Rahimpour, The effect of the application of graphene in the blocking layer structure to increase efficiency of perovskite solar cell, The 33rd National Conference on Physics of Iran, 2017. (in persian)
[33] J. T. W. Wang,  J. M. Ball, E. M. Barea, A. Abate, J. A. A. Webber, J.  Huang,  M. Saliba, I. M. Sero, J. Bisquert, H. J. Snaith, R. J. Nicholas, Low-Temperature Processed Electron Collection Layers of Graphene/TiO2 Nanocomposites in Thin Film Perovskite Solar Cells, Nano Letters, Vol. 14, No. 2, pp. 724−730, 2014.
[34] S. L. Mortazavifar,M. R. Salehi, M. Shahraki, E. Abiri, Optimization of light absorption in ultrathin elliptical silicon nanowire arrays for solar cell applications, Journal of Modern Optics, Vol. 69, No. 7, pp. 368-380, 2022.
[35] P. Löper, M. Stuckelberger, B. Niesen, J. Werner, M. Filipič, S. J. Moon, J. H. Yum, M. Topič, S. D. Wolf, C. Ballif, Complex Refractive Index Spectra of CH3NH3PbI3 Perovskite Thin Films Determined by Spectroscopic Ellipsometry and Spectrophotometry, The Journal of Physical Chemistry Letters, Vol. 6, No. 1, pp. 66-71, 2014.
[36] I. M. D. L. Santos, H. J. C. Marrero, M. A. R. Sánchez, L. H. Difur, F. J. S. Rodríguez, M. Courel, H. Hu, Optimization of CH3NH3PbI3 perovskite solar cells: A theoretical and experimental study, Solar Energy, Vol. 199, pp. 198-205, 2020.
 [37] M. R. Bonyadi, Z. Michalewicz, Particle Swarm Optimization for Single Objective Continuous Space Problems: A Review, Evolutionary Computation, Vol. 25, No. 1, pp. 1-54, 2017.

  • Receive Date 30 July 2025
  • Revise Date 30 October 2025
  • Accept Date 01 December 2025